Autor: |
Edgar Ignacio López Gómez, Kaveh Edalati, Diego Davi Coimbrão, Flávio José Antiqueira, Guilherme Zepon, Jorge M. Cubero-Sesin, Walter José Botta |
Jazyk: |
angličtina |
Rok vydání: |
2020 |
Předmět: |
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Zdroj: |
AIP Advances, Vol 10, Iss 5, Pp 055222-055222-6 (2020) |
Druh dokumentu: |
article |
ISSN: |
2158-3226 |
DOI: |
10.1063/5.0009456 |
Popis: |
Magnesium and hafnium, two hydride-forming and biocompatible metals with hexagonal close-packed crystal structures, are thermodynamically immiscible even in the liquid form. In this study, these two elements were mechanically mixed by high-pressure torsion straining, and a new FCC (face-centered cubic) phase was formed although these two elements do not form the FCC phase even under high pressure or at high temperature. Microstructural examination by scanning-transmission electron microscopy combined with an ASTAR automatic crystal orientation and phase mapping technique confirmed that the FCC phase was stabilized mainly in the Hf-rich nanograins with localized supersaturation. Attempts to control the phase transformations under a hydrogen atmosphere to produce ternary magnesium–hafnium hydrides for hydrogen storage applications were unsuccessful; however, the material exhibited enhanced hardness to an acceptable level for some biomedical applications. |
Databáze: |
Directory of Open Access Journals |
Externí odkaz: |
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