Activation of peroxymonosulfate by Co3Sn2 with Co(II)-enriched amorphous layer for efficient removal of RhB pollutant

Autor: Jianyu Qu, Chengxin Qin, Yan Chen, Fangjun Ding, Yingxue Zhang, Ganen Pan, Xingliang Xu, Xiurong Su
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Catalysis Communications, Vol 151, Iss , Pp 106281- (2021)
Druh dokumentu: article
ISSN: 1873-3905
DOI: 10.1016/j.catcom.2021.106281
Popis: Co3Sn2 with Co(II)-enriched amorphous layer was fabricated through reduction of Sn2+ under hydrothermal conditions. The material exhibited excellent performance for the activation of peroxymonosulfate (PMS) for Rhodamine B (RhB) removal. Almost 100% of RhB was removed using Co3Sn2/PMS within 10 min with an apparent rate constant of kapp = 0.515 min−1, which was higher than other cobalt-based catalysts. This performance of Co3Sn2 is suggested to be a synergistic effect between the Co(II)-layer with abundant active sites and the metallic core with excellent electron conductivity. Several pivotal parameters were investigated. Sulfate radicals and hydroxyl radicals were proven to be major oxidative species.
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