| Autor: |
Xiao, Mingxuan, Wang, Wei, Liu, Wenjing, Li, Zheng, Tang, Shui-Jing, Xiao, Yun-Feng |
| Rok vydání: |
2024 |
| Předmět: |
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| Druh dokumentu: |
Working Paper |
| Popis: |
Optical resonators have shown outstanding abilities to tailor chemical landscapes through enhanced light-matter interaction between confined optical modes and molecule vibrations. We propose a theoretical model to study cooperative vibrational strong coupling in an open quantum system. The non-equilibrium stochastic molecular dynamics in an optical cavity with an auxiliary ensemble is investigated. It shows that coupling with a cavity mode introduces an additional colored noise and a negative feedback, both of which enable control over thermalization rates (i.e. the lifetime of excitation) of reactive molecules. Our work offers a pathway to steer stability of chemical bonds for chemical reactivity under cooperative vibrational strong coupling. |
| Databáze: |
arXiv |
| Externí odkaz: |
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