Stabilization of lead-free bulk CsSnI$_3$ perovskite thermoelectrics via incorporating of TiS$_3$ nanoribbon clusters

Autor: Ivanova, Alexandra, Luchnikov, Lev, Golikova, Margarita, Muratov, Dmitry S., Saranin, Danila, Khanina, Aleksandra, Gostishchev, Pavel, Khovaylo, Vladimir
Rok vydání: 2024
Předmět:
Druh dokumentu: Working Paper
Popis: The intense research for efficient low-temperature thermoelectric materials motivates the exploration of innovative compounds and composite systems. This study examines the effects of integrating low-dimensional titanium trisulfide (TiS$_3$) into bulk tin-based halide perovskites (CsSnI$_3$) for use in thermoelectric applications. The addition of small amounts of two-dimensional titanium trisulfide (TiS$_3$) to bulk tin-based halide perovskites (CsSnI$_3$) significantly enhanced the structural stability of the composite material and suppressed oxidation processes. The CsSnI$_3$-TiS$_3$ composites demonstrated stabilization of temperature-dependent electrical properties (conductivity and Seebeck coefficient). This study provides valuable insights into the promising approach of using low-dimensional TiS3 as an additive to stabilize the thermoelectric performance of CsSnI$_3$.
Comment: 11 pages, 4 figures
Databáze: arXiv