Anomalous thermal oxidation of gadolinium thin films deposited on silicon by high pressure sputtering

Autor: Pampillón, María Ángela, Feijoo, Pedro Carlos, Andrés, Enrique San, Lucía, María Luisa, Toledano-Luque, María
Rok vydání: 2024
Předmět:
Zdroj: Microelectronic Engineering 88 (2011) 2991-2996
Druh dokumentu: Working Paper
DOI: 10.1016/j.mee.2011.04.058
Popis: Thin gadolinium metallic layers were deposited by high-pressure sputtering in pure Ar atmosphere. Subsequently, in situ thermal oxidation was performed at temperatures ranging from 150 to 750 $^\circ$C. At an oxidation temperature of 500 $^\circ$C the films show a transition from monoclinic structure to a mixture of monoclinic and cubic. Regrowth of interfacial SiO$_x$ is observed as temperature is increased, up to 1.6 nm for 750 $^\circ$C. This temperature yields the lowest interface trap density, 4e10 eV$^{-1}$ cm$^{-2}$, but the effective permittivity of the resulting dielectric is only 7.4. The reason of this low value is found on the oxidation mechanism, which yields a surface with located bumps. These bumps increase the average thickness, thus reducing the capacitance and therefore the calculated permittivity.
Comment: 22 pages, 7 figures, 1 table
Databáze: arXiv