Hidden Relaxation Term in Approximate Treatments of Responses to Electric and Magnetic Fields

Autor:	Desmarais, Jacques K.
Rok vydání:	2023
Předmět:	Condensed Matter - Materials Science Condensed Matter - Strongly Correlated Electrons Physics - Chemical Physics
Druh dokumentu:	Working Paper
Popis:	Recently a generalization of the ``\textit{modern theory of orbital magnetization}'' to include non-local Hamiltonians (e.g. hybrid functionals of the generalized Kohn-Sham theory) was provided for magnetic response properties. Results indicated inequivalence between sampling of direct and reciprocal spaces for those calculations far from the complete basis set limit. We show that this can be explained by a hidden ``relaxation'' contribution to the reciprocal-space derivatives. The missing relaxation term is shown to (generally) affect the results of calculations of not only magnetic, but also electric response properties, within the context of the ``\textit{modern theory of polarization}''. Necessary conditions are provided to permit avoiding the calculation of the hidden relaxation term.
Databáze:	arXiv
Externí odkaz:	http://arxiv.org/abs/2308.15435 Zobrazit plný text záznamu View this record from Arxiv