Investigation about the electrochemical reduction in 3YSZ, related phase transition and consequences

Autor:	Bechteler, C., Todd, R. I.
Rok vydání:	2023
Předmět:	Condensed Matter - Materials Science
Druh dokumentu:	Working Paper
Popis:	In this research the electrochemical reduction of 3YSZ was investigated in various atmospheres with different oxygen partial pressures under an electric field of 25 V/cm at an environmental temperature of 800 {\deg}C. At a certain oxygen partial pressure insufficient incorporation of oxygen in the sample led to electrochemical reduction of YSZ which shows two clearly distinguishable states. First, greying of the material without a significant change in properties was detected which then transitioned into a second stage where a fundamental phase transition in the material happened within seconds from tetragonal 3YSZ towards FCC rocksalt ZrO or ZrON, dependent on the atmosphere. This phase transition is accompanied by blackening of the material, sudden increase in electrical conductivity, current concentration, and an obvious change in Raman spectrum. Comment: 17 pages, 5 figures
Databáze:	arXiv
Externí odkaz:	http://arxiv.org/abs/2307.03557 Zobrazit plný text záznamu View this record from Arxiv