Formation of Core-Shell Precipitates in off-stochiometric Ni-Mn-Sn Heusler alloys probed through the induced Sn-moment

Autor: Eggert, Benedikt, Çakır, Aslı, Günzing, Damian, Josten, Nicolas, Scheibel, Franziska, Brand, Richard A., Farle, Michael, Acet, Mehmet, Wende, Heiko, Ollefs, Katharina
Rok vydání: 2023
Předmět:
Druh dokumentu: Working Paper
Popis: The Shell-ferromagnetic effect originates from the segregation process in off-stochiometric Ni-Mn-based Heusler. In this work, we investigate the precipitation process of L2$_1$-ordered Ni$_2$MnSn and L1$_0$-ordered NiMn in off-stochiometric Ni$_{50}$Mn$_{45}$Sn$_{5}$ during temper annealing, by X-ray diffraction (XRD) and $^{119}$Sn M\"ossbauer spectroscopy. While XRD probes long-range ordering of the lattice structure, M\"ossbauer spectroscopy probes nearest-neighbour interactions, reflected in the induced Sn magnetic moment. As shown in this work, the induced magnetic Sn moment can be used as a detector for microscopic structural changes and is, therefore, a powerful tool for investigating the formation of nano-precipitates. Similar research can be performed in the future, for example, on different pinning type magnets like Sm-Co or Nd-Fe-B.
Comment: 13 pages
Databáze: arXiv