Formation of Core-Shell Precipitates in off-stochiometric Ni-Mn-Sn Heusler alloys probed through the induced Sn-moment
Autor: | Eggert, Benedikt, Çakır, Aslı, Günzing, Damian, Josten, Nicolas, Scheibel, Franziska, Brand, Richard A., Farle, Michael, Acet, Mehmet, Wende, Heiko, Ollefs, Katharina |
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Rok vydání: | 2023 |
Předmět: | |
Druh dokumentu: | Working Paper |
Popis: | The Shell-ferromagnetic effect originates from the segregation process in off-stochiometric Ni-Mn-based Heusler. In this work, we investigate the precipitation process of L2$_1$-ordered Ni$_2$MnSn and L1$_0$-ordered NiMn in off-stochiometric Ni$_{50}$Mn$_{45}$Sn$_{5}$ during temper annealing, by X-ray diffraction (XRD) and $^{119}$Sn M\"ossbauer spectroscopy. While XRD probes long-range ordering of the lattice structure, M\"ossbauer spectroscopy probes nearest-neighbour interactions, reflected in the induced Sn magnetic moment. As shown in this work, the induced magnetic Sn moment can be used as a detector for microscopic structural changes and is, therefore, a powerful tool for investigating the formation of nano-precipitates. Similar research can be performed in the future, for example, on different pinning type magnets like Sm-Co or Nd-Fe-B. Comment: 13 pages |
Databáze: | arXiv |
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