Diatomic molecule in a strong infrared laser field: level-shifts and bond-length change due to laser-dressed Morse potential

Autor: Varró, Sándor, Hack, Szabolcs, Paragi, Gábor, Földi, Péter, Barna, Imre F., Czirják, Attila
Rok vydání: 2023
Předmět:
Druh dokumentu: Working Paper
DOI: 10.1088/1367-2630/acde9e
Popis: We present a general mathematical procedure to handle interactions described by a Morse potential in the presence of a strong harmonic excitation. We account for permanent and field-induced terms and their gradients in the dipole moment function, and we derive analytic formulae for the bond-length change and for the shifted energy eigenvalues of the vibrations, by using the Kramers-Henneberger frame. We apply these results to the important cases of $\mathrm{H}_{2}$ and $\mathrm{LiH}$, driven by a near- or mid-infrared laser in the $10^{13}$ $\mathrm{ W/cm^2}$ intensity range.
Databáze: arXiv