| Autor: |
Chandran, Suraj S., Wu, Yanze, Subotnik, Joseph E. |
| Rok vydání: |
2022 |
| Předmět: |
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| Druh dokumentu: |
Working Paper |
| DOI: |
10.1021/acs.jpca.2c06149 |
| Popis: |
We investigate spin-dependent electron transfer in the presence of a Duschinskii rotation. In particular, we propagate dynamics for a two-level model system for which spin-orbit coupling introduces an interstate coupling of the form $e^{iWx}$, which is both position(x)-dependent and complex-valued. We demonstrate that two-level systems coupled to Brownian oscillators with Duschinskii rotations (and thus entangled normal modes) can produce marked increases in transient spin polarization relative to two-level systems coupled to simple shifted harmonic oscillators. These conclusions should have significant relevance for modeling the effect of nuclear motion on chiral induced spin selectivity. |
| Databáze: |
arXiv |
| Externí odkaz: |
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