Cation-Dependent Nonadiabaticity in Proton-Coupled Electron Transfer at Electrified Solid-Liquid Interfaces

Autor:	Kumeda, Tomoaki, Sakaushi, Ken
Rok vydání:	2022
Předmět:	Physics - Chemical Physics
Druh dokumentu:	Working Paper
Popis:	Here we report an observation of cation-dependent nonadiabaticity in a proton-coupled electron transfer electrode process (PCET) during hydrogen evolution at electrified interfaces of Au(111) single-crystal electrode and electrolytes by employing electrochemical kinetic isotope effect analysis at ultra-clean/well-defined systems to investigate quantum-to-classical transition (QCT) in highly accuracy. Comment: 14 pages, 4 figures, version 1
Databáze:	arXiv
Externí odkaz:	http://arxiv.org/abs/2207.00138 Zobrazit plný text záznamu View this record from Arxiv