Self-broadening and self-shift in the $\mathbf{3\nu_{2}}$ band of ammonia from mid-infrared-frequency-comb spectroscopy

Autor: Yang, Guang, de Oliveira, Vinicius Silva, Laumer, Dominic, Heyl, Christoph M., Yachmenev, Andrey, Hartl, Ingmar, Küpper, Jochen
Rok vydání: 2022
Předmět:
Druh dokumentu: Working Paper
DOI: 10.1016/j.jms.2023.111744
Popis: We report the broadband absorption spectrum of the $3\nu_{2}$ band of $^{14}$NH$_{3}$ near 4 $\mu m$. The data were recorded using a mid-infrared frequency comb coupled to a homebuilt Fourier-transform spectrometer with a resolution of 0.00501 $cm^{-1}$. Line positions, line intensities, self-broadening, and self-shift parameters for six rovibrational lines were determined at room temperature ($T=296$ K). Comparison with HITRAN 2016 shows good agreement at improved precision. The high precision and the rapid tunability of our experiment enables advanced fast spectroscopy of molecular gases.
Databáze: arXiv