Octave-spanning 1 emission across the visible spectrum from single crystalline 1,3,5,7-tetrakis-($p$-methoxyphenyl)adamantane
| Autor: | Müller, Marius J., Ziese, Ferdinand, Belz, Jürgen, Hüppe, Franziska, Gowrisankar, Saravanan, Bernhardt, Bastian, Schwan, Sebastian, Schreiner, Doreen Mollenhauer Peter R., Volz, Kerstin, Sanna, Simone, Chatterjee, Sangam |
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| Rok vydání: | 2022 |
| Předmět: | |
| Druh dokumentu: | Working Paper |
| DOI: | 10.1364/OME.461427 |
| Popis: | Sustainable efficient light emitter based solely on elements-of-hope are needed to replace current compounds based on less-abundant materials. Functionalized diamondoids are a potential solution for this challenge as they offer efficient, octave-spanning emission across the visible spectrum in their single-crystalline form. Its large quantum efficiency increases towards higher-than-ambient temperatures to beyond 7 %. The stability beyond 200 {\deg}C renders such functionalized diamondoids as sustainable phosphors for LED applications. Detailed structural and theoretical investigations suggest a crucial role of exciton states accompanied by structural modifications (self-trapped excitons) in the emission process. Comment: 13 pages, 8 figures |
| Databáze: | arXiv |
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