Resistivity testing of palladium dilution limits in CoPd alloys for hydrogen storage

Autor: Das, S. S., Kopnov, G., Gerber, A.
Rok vydání: 2022
Předmět:
Zdroj: Materials 15, 111 (2022)
Druh dokumentu: Working Paper
DOI: 10.3390/ma15010111
Popis: Palladium satisfies most of the requirements for an effective hydrogen storage material with two major drawbacks: it has a relatively low gravimetric hydrogen density and is prohibitively expensive for large-scale applications. Pd-based alloys should be considered as possible alternatives to a pure Pd. The question is how much one can dilute the Pd concentration in a variety of candidate materials while preserving hydrogen absorption capability. We demonstrate that the resistivity measurements of thin-film alloy samples can be used for a qualitative high-throughput screening and study of the hydrogen-absorbing properties over the entire range of palladium concentrations. Contrary to palladium-rich alloys where additional hydrogen scattering indicates a degree of hydrogen content, the diluted alloy films respond by a decrease of resistance due to their thickness expansion. Evidence of significant hydrogen absorption was found in thin CoPd films diluted to just 20% of Pd.
Databáze: arXiv