| Autor: |
Liebenthal, Marcus D., Vu, Nam, DePrince III, A. Eugene |
| Rok vydání: |
2021 |
| Předmět: |
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| Druh dokumentu: |
Working Paper |
| DOI: |
10.1063/5.0078795 |
| Popis: |
The electron attachment variant of equation-of-motion coupled-cluster theory (EOM-EA-CC) is generalized to the case of strong light-matter coupling within the framework of cavity quantum electrodynamics (QED). The resulting EOM-EA-QED-CC formalism provides an ab initio, correlated, and non-perturbative description of cavity-induced effects in many-electron systems that complements other recently proposed cavity-QED-based extensions of coupled-cluster theory. Importantly, this work demonstrates that QED generalizations of EOM-CC theory are useful frameworks for exploring particle non-conserving sectors of Fock space, thereby establishing a path forward for the simultaneous description of both strong electron-electron and electron-photon correlation effects. |
| Databáze: |
arXiv |
| Externí odkaz: |
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