Finite-size effects and thermodynamic limit in one-dimensional Janus fluids

Autor:	Fantoni, R., Maestre, M. A. G., Santos, A.
Rok vydání:	2021
Předmět:	Condensed Matter - Statistical Mechanics Condensed Matter - Soft Condensed Matter Physics - Chemical Physics
Zdroj:	J. Stat. Mech., 103210 (2021)
Druh dokumentu:	Working Paper
DOI:	10.1088/1742-5468/ac2897
Popis:	The equilibrium properties of a Janus fluid made of two-face particles confined to a one-dimensional channel are revisited. The exact Gibbs free energy for a finite number of particles $N$ is exactly derived for both quenched and annealed realizations. It is proved that the results for both classes of systems tend in the thermodynamic limit ($N\to\infty$) to a common expression recently derived (Maestre M A G and Santos A 2020 J Stat Mech 063217). The theoretical finite-size results are particularized to the Kern--Frenkel model and confirmed by Monte Carlo simulations for quenched and (both biased and unbiased) annealed systems. Comment: 23 one-column pages, 6 figures; v2: minor changes
Databáze:	arXiv
Externí odkaz:	http://arxiv.org/abs/2107.13883 Zobrazit plný text záznamu View this record from Arxiv