| Autor: |
Kamenev, Konstantin V., Courac, Alexandre, Sokolov, Petr S., Baranov, Andrei N., Sharikov, Felix Yu., Solozhenko, Vladimir L. |
| Rok vydání: |
2021 |
| Předmět: |
|
| Zdroj: |
Solids, 2 [1] 121-128 (2021) |
| Druh dokumentu: |
Working Paper |
| DOI: |
10.3390/solids2010007 |
| Popis: |
Low-temperature heat capacities (Cp) of nanostructured rock salt (rs-ZnO) and wurtzite (w-ZnO) polymorphs of zinc oxide were measured in the 2-315 K temperature range. No significant influence of nanostructuring on Cp of w-ZnO has been observed. The measured Cp of rock salt ZnO is lower than that of wurtzite ZnO below 100 K and is higher above this temperature. Using available thermodynamic data, we established that the equilibrium pressure between nanocrystalline w-ZnO and rs-ZnO is close to 4.6 GPa at 300 K (half as much as the onset pressure of direct phase transformation) and slightly changes with temperature up to 1000 K. |
| Databáze: |
arXiv |
| Externí odkaz: |
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