Observation of an electric quadrupole transition in a negative ion: Experiment and Theory

Autor: Walter, C. W., Spielman, S. E., Ponce, R., Gibson, N. D., Yukich, J. N., Cheung, C., Safronova, M. S.
Rok vydání: 2020
Předmět:
Zdroj: Phys. Rev. Lett. 126, 083001 (2021)
Druh dokumentu: Working Paper
DOI: 10.1103/PhysRevLett.126.083001
Popis: The first direct experimental observation of an electric quadrupole ($\textit{E}$2) transition between bound states of an atomic negative ion has been made. The transition was observed in the negative ion of bismuth by resonant (1+1) photodetachment from Bi$^-$ $^3\textit{P}_2$ via excitation of the Bi$^-$ $^3\textit{P}_0$ fine structure state. The $\textit{E}$2 transition properties were independently calculated using a hybrid theoretical approach to account for the strong multi-level electron interactions and relativistic effects. The experimental and theoretical results are in excellent agreement, providing valuable new insights into this complex system and forbidden transitions in negative ions.
Comment: 7 pages, 3 figures, 4 tables
Databáze: arXiv