Ni-Sn intermetallics as efficient buffering matrix of Si anodes in Li-ion batteries
| Autor: | Azib, Tahar, Bibent, Nicolas, Latroche, Michel, Fischer, Florent, Jumas, Jean-Claude, Olivier-Fourcade, Josette, Jordy, Christian, Lippens, Pierre-Emmanuel, Cuevas, Fermin |
|---|---|
| Rok vydání: | 2020 |
| Předmět: | |
| Zdroj: | J. Mater. Chem. A, 8 (2020) 18132-18142 |
| Druh dokumentu: | Working Paper |
| DOI: | 10.1039/D0TA06047J |
| Popis: | For a successful integration of silicon in high-capacity anodes of Li-ion batteries, its intrinsic capacity decay on cycling due to severe volume swelling should be minimized. In this work, Ni-Sn intermetallics are studied as buffering matrix during reversible lithiation of Si-based anodes. Si/Ni-Sn composites have been synthetized by mechanical milling using C and Al as process control agents. Ni3Sn4, Ni3Sn2 intermetallics and their bi-phasic mixture were used as constituents of the buffering matrix. The structure, composition and morphology of the composites have been analyzed by X-ray diffraction (XRD), 119Sn Transmission M\"ossbauer Spectroscopy (TMS) and scanning electron microscopy (SEM). They consist of ~ 150 nm Si nanoparticles embedded in a multi-phase matrix, the nanostructuration of which improves on increasing the Ni3Sn4 amount. The electrochemical properties of the composites were analyzed by galvanostatic cycling in half-cells. Best results for practical applications are found for the bi-phasic matrix Ni3Sn4-Ni3Sn2 in which Ni3Sn4 is electrochemically active while Ni3Sn2 is inactive. Low capacity loss, 0.04 %/cycle, and high coulombic efficiency, 99.6%, were obtained over 200 cycles while maintaining a high reversible capacity above 500 mAh/g at moderate regime C/5 Comment: 11 pages, 7 figures, 5 tables |
| Databáze: | arXiv |
| Externí odkaz: |
|