Monomeric, Two-Dimensionally Ordered WO$_3$ Clusters on Anatase TiO$_2$(101)

Autor: Xu, Tao, Adamsen, Kræn C., Falsig, Hanne, Rasmussen, Søren B., Li, Zheshen, Wendt, Stefan, Lauritsen, Jeppe V.
Rok vydání: 2020
Předmět:
Zdroj: Phys. Rev. Materials 4, 124004 (2020)
Druh dokumentu: Working Paper
DOI: 10.1103/PhysRevMaterials.4.124004
Popis: We combined scanning tunneling microscopy (STM) and X-ray photoelectron spectroscopy (XPS) experiments with density functional theory (DFT) calculations to study dispersed tungsta clusters on anatase TiO$_2$(101). Following two different preparation methods, we found that monomeric WO$_3$ species are the most stable configuration rather than WO$_3$ trimers, (WO$_3$)$_3$. The WO$_3$ monomers form tetrahedral WO$_4$ structures on anatase TiO$_2$(101), with one W$-$O bond and two W$-$O$-$Ti linkages per WO$_3$ monomer. Locally, the WO$_3$ monomers form well-ordered (2$\times$1) structures. The discovered geometric structure of WO$_3$ on anatase TiO$_2$(101) opens up numerous opportunities for fundamental studies addressing tungsta and accurate structure activity studies of WO$_3$/TiO$_2$ model catalysts.
Databáze: arXiv