Theoretical and experimental comparative study of nonlinear properties of imidazolium cation based ionic liquids

Autor:	Ferreira, Vinícius Castro, Zanchet, Letícia, Monteiro, Wesley Formentin, da Trindade, Letícia Guerreiro, de Souza, Michèle Oberson, Correia, Ricardo Rego Bordalo
Rok vydání:	2020
Předmět:	Condensed Matter - Materials Science Physics - Chemical Physics Physics - Optics
Druh dokumentu:	Working Paper
Popis:	This work describes the experimental and theoretical study of the nonlinear optical properties of the imidazolium cation based ionic liquids and the corresponding thermo-optical parameters. Experimental results of nonlinear optical properties, such as nonlinear refractive index and thermo-optical properties are determined by Z-scan and EZ-scan techniques with a femtosecond laser source. Theoretical simulations of linear and nonlinear optical properties performed by density functional theory (DFT) are discussed, in terms of polarizability, the first and second-order of hyperpolarizability. A correlation between the theoretical and experimental results is presented, where the variation of the signals of each ionic liquid can be compared with their nonlinear optical properties. Comment: 25 pages, 5 figures, 5 tables
Databáze:	arXiv
Externí odkaz:	http://arxiv.org/abs/2008.01486 Zobrazit plný text záznamu View this record from Arxiv