Spatial Separation of the Conformers of Methyl Vinyl Ketone
| Autor: | Wang, Jia, Kilaj, Ardita, He, Lanhai, Długołęcki, Karol, Willitsch, Stefan, Küpper, Jochen |
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| Rok vydání: | 2020 |
| Předmět: | |
| Zdroj: | J. Phys. Chem. A 2020 |
| Druh dokumentu: | Working Paper |
| DOI: | 10.1021/acs.jpca.0c05893 |
| Popis: | Methyl vinyl ketone (C$_4$H$_6$O) is a volatile, labile organic compound of importance in atmospheric chemistry. We prepared a molecular beam of methyl vinyl ketone with a rotational temperature of 1.2(2)~K and demonstrated the spatial separation of the \emph{s-cis} and \emph{s-trans} conformers of methyl vinyl ketone using the electrostatic deflector. The resulting sample density was $1.5(2)\times10^{8}~\text{cm}^{-3}$ for the direct beam in the laser ionization region. These conformer-selected methyl vinyl ketone samples are well suited for conformer-specific chemical reactivity studies such as in Diels-Alder cycloaddition reactions. Comment: Accepted by J. Phys. Chem. A. Manuscript: 5 pages, 3 figures; Supporting information: 3 pages, 5 figures |
| Databáze: | arXiv |
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