Revealing a full quantum ladder by nonlinear spectroscopy
| Autor: | Abramavicius, Darius |
|---|---|
| Rok vydání: | 2020 |
| Předmět: | |
| Zdroj: | Lith. J. Phys. 60, 154-166 2020 |
| Druh dokumentu: | Working Paper |
| DOI: | 10.3952/physics.v60i3.4302 |
| Popis: | Coherent two-dimensional spectroscopy in IR or visible region is very effective for studying correlations, energy relaxation/transfer pathways in complex multi-chromophore or multi-mode systems. However it is usually restricted up to two-quanta excitations and their properties. In this paper an arbitrary level of excitation is suggested as the utility to scan nonlinear potential surfaces of quantum systems up to a desired excitation degree. This can be achieved by a simple three-pulse laser spectroscopy approach. Accurate evaluation of high-level anharmonicities as well as transition amplitudes can be directly obtained. Additionally, questions regarding the quantum nature of the probed system can be addressed by studying absolute peak positions. Comment: 11 pages, 4 figures, original manuscript |
| Databáze: | arXiv |
| Externí odkaz: |
|