Strictly Non-Adiabatic Quantum Control of the Acetylene Dication Using an Infrared Field
| Autor: | Liekhus-Schmaltz, Chelsea, Zhu, Xiaolei, McCracken, Gregory A., Cryan, James P., Martinez, Todd, Bucksbaum, Philip H. |
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| Rok vydání: | 2020 |
| Předmět: | |
| Druh dokumentu: | Working Paper |
| DOI: | 10.1063/5.0007058 |
| Popis: | We demonstrate the existence of a strictly non-adiabatic control pathway in deprotonation of the acetylene dication. This pathway is identified experimentally by measuring a kinetic energy shift in an ion coincidence experiment. We use a TDSE simulation to identify which properties most strongly affect our control. We find that resonant control around conical intersections is limited by the speed of non-adiabatic dynamics. Comment: 7 pages, 3 figures |
| Databáze: | arXiv |
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