Low work function in the 122-family of iron-based superconductors

Autor: Pfau, H., Soifer, H., Sobota, J. A., Gauthier, A., Rotundu, C. R., Palmstrom, J. C., Fisher, I. R., Chen, G. -Y., Wen, H. -H., Shen, Z. -X., Kirchmann, P. S.
Rok vydání: 2020
Předmět:
Zdroj: Phys. Rev. Materials 4, 034801 (2020)
Druh dokumentu: Working Paper
DOI: 10.1103/PhysRevMaterials.4.034801
Popis: We determine the work functions of the iron arsenic compounds $A$Fe$_2$As$_2$ ($A=\mathrm{Ca, Ba, Cs}$) using photoemission spectroscopy to be 2.7 eV for CaFe$_2$As$_2$, 1.8 eV for BaFe$_2$As$_2$, and 1.3 eV for CsFe$_2$As$_2$. The work functions of these 122 iron-based superconductors track those of the elementary metal $A$ but are substantially smaller. The most likely explanation of this observation is that the cleaving surface exposes only half an $A$-layer. The low work function and good photoemission cross section of BaFe$_2$As$_2$ and CsFe$_2$As$_2$ enable photoemission even from a common white LED light.
Databáze: arXiv