Chemical-Vapor-Deposited Graphene as a Thermally Conducting Coating

Autor: Tortello, Mauro, Pasternak, Iwona, Zeranska-Chudek, Klaudia, Strupinski, Wlodek, Gonnelli, Renato S., Fina, Alberto
Rok vydání: 2019
Předmět:
Zdroj: ACS Appl. Nano Mater. 2019, 2, 2621-2633
Druh dokumentu: Working Paper
DOI: 10.1021/acsanm.8b02243
Popis: We performed Scanning Thermal Microscopy measurements on single layers of chemical-vapor-deposited -CVD- graphene supported by different substrates, namely SiO2, Al2O3 and PET using a double-scan technique to remove the contribution to the heat flux through the air and the cantilever. Then, by adopting a simple lumped-elements model, we developed a new method that allows determining, through a multi-step numerical analysis, the equivalent thermal properties of thermally conductive coatings of nanometric thickness. In this specific case we found that our CVD graphene is thermally equivalent, for heat injection perpendicular to the graphene planes, to a coating material of conductivity Keff=2.5+-0.3 mK and thickness teff=3.5+-0.3 nm in perfect contact with the substrate. For the SiO2 substrate, we also measured stacks made of 2 and 4 CVD monolayers and we found that the effective thermal conductivity increases with increasing number of layers and, with a technologically achievable number of layers, is expected to be comparable to that of one order of magnitude-thicker metallic thin films. This study provides a powerful method for characterizing the thermal properties of graphene in view of several thermal management applications.
Databáze: arXiv