Organic nanotubes created from mesogenic derivatives

Autor: Novotna, Vladimira, Hamplova, Vera, Lejcek, Lubor, Pociecha, Damian, Cigl, Martin, Fekete, Ladislav, Glogarova, Milada, Bednarova, Lucie, Majewski, Pawel W., Gorecka, Ewa
Rok vydání: 2019
Předmět:
Zdroj: Nanoscale Advances, 2019,1, 2835 - 2839
Druh dokumentu: Working Paper
DOI: 10.1039/c9na00175a
Popis: A facile route to prepare the nanotubes from rod-like mesogens dissolved in typical organic solvents is reported. For selected types of chiral rod-like molecules, both enantiomers as well as the racemic mixtures formed the nanotubes by slow evaporation from a solution, regardless of the solvent, concentration or deposition type. Obtained supramolecular assemblies were studied using AFM and SEM techniques. Additional methods (IR, UV-Vis spectroscopy and x-ray diffraction) were applied to characterize the observed nanotubes. The difference in the surface tension at opposite crystallite surfaces is suggested as a possible mechanism for the nanotube nucleation.
Comment: 5 pages, 5 figures
Databáze: arXiv