Nonadiabatic QED correction to the dissociation energy of the hydrogen molecule

Autor: Puchalski, M., Czachorowski, J. Komasa. P., Pachucki, K.
Rok vydání: 2018
Předmět:
Zdroj: Phys. Rev. Lett. 122, 103003 (2019)
Druh dokumentu: Working Paper
DOI: 10.1103/PhysRevLett.122.103003
Popis: The quantum electrodynamic correction to the energy of the hydrogen molecule has been evaluated without expansion in the electron-proton mass ratio. The obtained results significantly improve the accuracy of theoretical predictions reaching the level of 1 MHz for the dissociation energy, in a very good agreement with the parallel measurement [H\"olsch et al., Phys. Rev. Lett. 122, 103002 (2019)]. Molecular hydrogen has thus become a cornerstone of ultraprecise quantum chemistry, which opens perspectives for determination of fundamental physical constants from its spectra.
Comment: 5 pages
Databáze: arXiv