Open-Circuit Voltage Deficit in Cu2ZnSnS4 Solar Cells by Interface Band Gap Narrowing
Autor: | Park, Ji-Sang, Kim, Sunghyun, Hood, Samantha N., Walsh, Aron |
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Rok vydání: | 2018 |
Předmět: | |
Druh dokumentu: | Working Paper |
DOI: | 10.1063/1.5063793 |
Popis: | There is evidence that interface recombination in Cu2ZnSnS4 solar cells contributes to the open-circuit voltage deficit. Our hybrid density functional theory calculations suggest that electron-hole recombination at the Cu2ZnSnS4/CdS interface is caused by a deeper conduction band that slows electron extraction. In contrast, the bandgap is not narrowed for the Cu2ZnSnSe4/CdS interface, consistent with a lower open-circuit voltage deficit. Comment: 5 pages, 5 figures |
Databáze: | arXiv |
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