The first detections of the key prebiotic molecule PO in star-forming regions

Autor: Rivilla, Víctor M., Fontani, Francesco, Beltrán, Maite, Vasyunin, Anton, Caselli, Paola, Martín-Pintado, Jesús, Cesaroni, Riccardo
Rok vydání: 2018
Předmět:
Druh dokumentu: Working Paper
DOI: 10.1017/S1743921317008729
Popis: Phosphorus is a crucial element in prebiotic chemistry, especially the P$-$O bond, which is key for the formation of the backbone of the deoxyribonucleic acid. So far, PO had only been detected towards the envelope of evolved stars, and never towards star-forming regions. We report the first detection of PO towards two massive star-forming regions, W51 e1/e2 and W3(OH), using data from the IRAM 30m telescope. PN has also been detected towards the two regions. The abundance ratio PO/PN is 1.8 and 3 for W51 and W3(OH), respectively. Our chemical model indicates that the two molecules are chemically related and are formed via gas-phase ion-molecule and neutral-neutral reactions during the cold collapse. The molecules freeze out onto grains at the end of the collapse and desorb during the warm-up phase once the temperature reaches $\sim$35 K. The observed molecular abundances of 10$^{-10}$ are predicted by the model if a relatively high initial abundance of phosphorus, 5$\times$10$^{-9}$, is assumed.
Comment: To appear in "Astrochemistry VII -- Through the Cosmos from Galaxies to Planets", proceedings of the IAU Symposium No. 332, 2017, Puerto Varas, Chile. M. Cunningham, T. Millar and Y. Aikawa, eds. (6 pages)
Databáze: arXiv