| Autor: |
Nespoulous, Mathieu, Denoyel, Renaud, Antoni, Mickaël |
| Rok vydání: |
2018 |
| Předmět: |
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| Druh dokumentu: |
Working Paper |
| DOI: |
10.1021/acs.jpclett.8b00984 |
| Popis: |
The structural evolution of suspensions upon freezing is studied with optical microscopy in a suspended droplet configuration. Droplets have millimeter size and consist in an aqueous mixture of silica particles while the surroundings phase is hexane. Freeze-thaw cycles are applied to this system and a two-step freezing mechanism evidenced. A fast adiabatic growth of dendrites that invade the full droplets is first observed, and occurs within a few milliseconds. Then a slow process lasts for several seconds and corresponds to the release of solidification latent heat into the hexane phase. The striking feature of this work is to evidence that after the first freeze-thaw cycle flocculated microstructures are generated. When a second cycle is performed, microstructures further flocculate and generate, for dense silica suspensions, stable porous spheres of the size of the droplets. A phenomenological description based on repulsion or engulfment of particles by solidifying ice fronts is proposed. |
| Databáze: |
arXiv |
| Externí odkaz: |
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