An oxorhenium complex bearing a chiral cyclohexane-1-olato-2-thiolato ligand: synthesis, stereochemistry and theoretical study of parity violation vibrational frequency shifts
| Autor: | Saleh, Nidal, Bast, Radovan, Vanthuyne, Nicolas, Roussel, Christian, Saue, Trond, Darquié, Benoît, Crassous, Jeanne |
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| Rok vydání: | 2018 |
| Předmět: | |
| Zdroj: | Chirality 30, 147-156 (2018) |
| Druh dokumentu: | Working Paper |
| DOI: | 10.1002/chir.22785 |
| Popis: | In our effort towards measuring the parity violation energy difference between two enantiomers, a simple chiral oxorhenium complex 5 bearing enantiopure 2-mercaptocyclohexan-1-ol has been prepared as a potential candidate species. Vibrational circular dichroism revealed a chiral environment surrounding the rhenium atom, even though the rhenium is not a stereogenic centre itself, and enabled to assign the (1S,2S)-(-) and (1R,2R)-(+) absolute configuration for 5. For both compound 5 and complex 4, previously studied by us and bearing a propane-2-olato-3-thiolato ligand, relativistic calculations predict parity violating vibrational frequency differences of a few hundreds of millihertz, above the expected sensitivity attainable by a molecular beam Ramsey interferometer that we are constructing. Comment: 9 pages, 4 figures, 2 tables |
| Databáze: | arXiv |
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