High-pressure cell for simultaneous dielectric and neutron spectroscopy
| Autor: | Sanz, Alejandro, Hansen, Henriette Wase, Jakobsen, Bo, Pedersen, Ib H., Capaccioli, Simone, Adrjanowicz, Karolina, Paluch, Marian, Gonthier, Julien, Frick, Bernhard, Lelièvre-Berna, Eddy, Peters, Judith, Niss, Kristine |
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| Rok vydání: | 2017 |
| Předmět: | |
| Druh dokumentu: | Working Paper |
| DOI: | 10.1063/1.5007021 |
| Popis: | In this article we report on the design, manufacture and testing of a high-pressure cell for doing simultaneous dielectric and neutron spectroscopy. This cell is a unique tool for studying dynamics on different timescales, from kilo- to picoseconds, covering universal features such as the alpha relaxation and fast vibrations at the same time. The cell, constructed in cylindrical geometry, is made in high-strength aluminum alloy and operates up to 500 MPa in a temperature range between roughly 2 and 320 K. In order to measure the scattered neutron intensity and the sample capacitance simultaneously, a cylindrical capacitor is positioned within the bore of the high-pressure container. The capacitor consists of two concentric electrodes separated by insulating spacers. The performance of this setup has been successfully verified by collecting simultaneous dielectric and neutron spectroscopy data on dipropylene glycol, using both backscattering and time-of-flight instruments. We have carried out the experiments at different combinations of temperature and pressure in both supercooled liquid and glassy state. Comment: A.S. and H.W.H. contributed equally to this work |
| Databáze: | arXiv |
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