Possible Structural Transformation and Enhanced Magnetic Fluctuations in Exfoliated $\alpha$-RuCl$_3$

Autor: Zhou, Boyi, Wang, Yiping, Osterhoudt, Gavin B., Kelly, Paige, Mandrus, David, He, Rui, Burch, Kenneth S., Henriksen, Erik A.
Rok vydání: 2017
Předmět:
Zdroj: Journal of Physics and Chemistry of Solids 128, 291 (2019)
Druh dokumentu: Working Paper
DOI: 10.1016/j.jpcs.2018.01.026
Popis: We present initial Raman spectroscopy experiments on exfoliated flakes of $\alpha$-RuCl$_3$, from tens of nm thick down to single layers. Besides unexpectedly finding this material to be air stable, in the thinnest layers we observe the appearance with decreasing temperature of a symmetry-forbidden mode in crossed polarization, along with an anomalous broadening of a mode at 164 cm$^{-1}$ that is known to couple to a continuum of magnetic excitations. This may be due to an enhancement of magnetic fluctuations and evidence for a distorted honeycomb lattice in single- and bi-layer samples.
Databáze: arXiv