New Comment on Gibbs Density Surface of Fluid Argon: Revised Critical Parameters, L. V. Woodcock, Int. J. Thermophys. (2014) 35, 1770-1784

Autor:	Umirzakov, Ikhtier H.
Rok vydání:	2017
Předmět:	Condensed Matter - Statistical Mechanics
Druh dokumentu:	Working Paper
DOI:	10.1007/s10765-017-2331-6
Popis:	It is shown that the existence of single critical point of the fluid described by van der Waals equation of state is not the hypothesis and it is the consequence of the thermodynamic conditions of liquid-vapor phase equilibrium. It is also shown that the thermodynamic conditions of liquid-vapor phase equilibrium of the fluid give equalities to zero of first and second partial derivatives at constant temperature of pressure with respect to volume at critical point which are usual conditions of existence of critical point.
Databáze:	arXiv
Externí odkaz:	http://arxiv.org/abs/1705.08412 Zobrazit plný text záznamu View this record from Arxiv