Experimental Study of Heat Pump Thermodynamic Cycles Using CO 2 Based Mixtures -Methodology and First Results

Autor: Bouteiller, Paul, Terrier, Marie-France, Tobaly, Pascal
Rok vydání: 2017
Předmět:
Zdroj: TECHNOLOGIES AND MATERIALS FOR RENEWABLE ENERGY, ENVIRONMENT AND SUSTAINABILITY: TMREES16-Cnam, Nov 2016, Paris, France. AIP, AIP conference proceedings, 2017, TECHNOLOGIES AND MATERIALS FOR RENEWABLE ENERGY, ENVIRONMENT AND SUSTAINABILITY: TMREES16-Cnam
Druh dokumentu: Working Paper
DOI: 10.1063/1.4976271
Popis: The aim of this work is to study heat pump cycles, using CO 2 based mixtures as working fluids. Since adding other chemicals to CO 2 moves the critical point and generally equilibrium lines, it is expected that lower operating pressures as well as higher global efficiencies may be reached. A simple stage pure CO 2 cycle is used as reference, with fixed external conditions. Two scenarios are considered: water is heated from 10 {\textdegree}C to 65 {\textdegree}C for Domestic Hot Water scenario and from 30 {\textdegree}C to 35 {\textdegree}C for Central Heating scenario. In both cases, water at the evaporator inlet is set at 7 {\textdegree}C to account for such outdoor temperature conditions. In order to understand the dynamic behaviour of thermodynamic cycles with mixtures, it is essential to measure the fluid circulating composition. To this end, we have developed a non intrusive method. Online optical flow cells allow the recording of infrared spectra by means of a Fourier Transform Infra Red spectrometer. A careful calibration is performed by measuring a statistically significant number of spectra for samples of known composition. Then, a statistical model is constructed to relate spectra to compositions. After calibration, compositions are obtained by recording the spectrum in few seconds, thus allowing for a dynamic analysis. This article will describe the experimental setup and the composition measurement techniques. Then a first account of results with pure CO 2 , and with the addition of propane or R-1234yf will be given.
Databáze: arXiv
Popis
Abstrakt:The aim of this work is to study heat pump cycles, using CO 2 based mixtures as working fluids. Since adding other chemicals to CO 2 moves the critical point and generally equilibrium lines, it is expected that lower operating pressures as well as higher global efficiencies may be reached. A simple stage pure CO 2 cycle is used as reference, with fixed external conditions. Two scenarios are considered: water is heated from 10 {\textdegree}C to 65 {\textdegree}C for Domestic Hot Water scenario and from 30 {\textdegree}C to 35 {\textdegree}C for Central Heating scenario. In both cases, water at the evaporator inlet is set at 7 {\textdegree}C to account for such outdoor temperature conditions. In order to understand the dynamic behaviour of thermodynamic cycles with mixtures, it is essential to measure the fluid circulating composition. To this end, we have developed a non intrusive method. Online optical flow cells allow the recording of infrared spectra by means of a Fourier Transform Infra Red spectrometer. A careful calibration is performed by measuring a statistically significant number of spectra for samples of known composition. Then, a statistical model is constructed to relate spectra to compositions. After calibration, compositions are obtained by recording the spectrum in few seconds, thus allowing for a dynamic analysis. This article will describe the experimental setup and the composition measurement techniques. Then a first account of results with pure CO 2 , and with the addition of propane or R-1234yf will be given.
DOI:10.1063/1.4976271