Shape-dependent oriented trapping and scaffolding of plasmonic nanoparticles by topological defects for self-assembly of colloidal dimers in liquid crystals

Autor: Senyuk, Bohdan, Evans, Julian S., Ackerman, Paul J., Lee, Taewoo, Manna, Pramit, Vigderman, Leonid, Zubarev, Eugene R., van de Lagemaat, Jao, Smalyukh, Ivan I.
Rok vydání: 2016
Předmět:
Zdroj: Nano Letters 12, 955-963 (2012)
Druh dokumentu: Working Paper
DOI: 10.1021/nl204030t
Popis: We demonstrate scaffolding of plasmonic nanoparticles by topological defects induced by colloidal microspheres to match their surface boundary conditions with a uniform far-field alignment in a liquid crystal host. Displacing energetically costly liquid crystal regions of reduced order, anisotropic nanoparticles with concave or convex shapes not only stably localize in defects but also self-orient with respect to the microsphere surface. Using laser tweezers, we manipulate the ensuing nanoparticle-microsphere colloidal dimers, probing the strength of elastic binding and demonstrating self-assembly of hierarchical colloidal superstructures such as chains and arrays.
Databáze: arXiv