Spin-glass behavior and pyroelectric anomalies in a new lithium-based oxide, Li3FeRuO5

Autor:	Upadhyay, Sanjay Kumar, Paulose, P. L., Iyer, Kartik K, Sampathkumaran, E. V.
Rok vydání:	2016
Předmět:	Condensed Matter - Strongly Correlated Electrons Condensed Matter - Materials Science
Druh dokumentu:	Working Paper
DOI:	10.1039/C6CP04179E
Popis:	The results of dc and ac magnetization, heat-capacity, 57Fe Moessbauer spectroscopy, dielectric, pyroelectric current and isothermal magneto-capacitance measurements on a recently reported lithium-based oxide, Li3FeRuO6, related to LiCoO2-type rhombohedral structure (space group, R-3m) are presented. The results reveal that the compound undergoes spin-glass freezing below 15 K. There is a peak around 34 K in pyroelectric data, which can not be attributed to ferroelectricity, but to the phenomenon of thermally stimulated depolarization current. As revealed by magnetocapacitance data above and below magnetic ordering temperature, magnetic and electric dipoles appear to be coupled, thereby offering evidence for magnetodielectric coupling. Comment: Physical Chemistry Chemical Physics, in press. arXiv admin note: text overlap with arXiv:1607.08689
Databáze:	arXiv
Externí odkaz:	http://arxiv.org/abs/1608.02304 Zobrazit plný text záznamu View this record from Arxiv