Jahn-Teller induced nematic orbital order in tetragonal Sr$_2$VO$_4$

Autor: Teyssier, J., Giannini, E., Stucky, A., Cerný, R., Eremin, M. V., van der Marel, D.
Rok vydání: 2015
Předmět:
Druh dokumentu: Working Paper
DOI: 10.1103/PhysRevB.93.125138
Popis: Using high resolution X-Ray diffraction (XRD) on high purity powders, we resolved the structure and $ab$ symmetry of the intriguing compound \svo$ $ from room temperature down to 20 K to an unprecedented level of accuracy. Upon cooling, this new set of data unambiguously reveals a second order phase transition lowering the symmetry from tetragonal to orthorhombic at a temperature $T_{c2}=136$ K. The observation of an orthorhombic distortion of the $ab$-plane is attributed to nematic phase formation supported by local Jahn-Teller (JT) dynamical instability. At $T_{N}=105$ K, spins order and at $T_{c1}=100$ K the tetragonal structure is recovered with an elongated c-axis.
Comment: 4 pages, 2 figures
Databáze: arXiv