Dynamics of gas phase Ne$^*$ + NH$_3$ and Ne$^*$ + ND$_3$ Penning ionization at low temperatures

Autor: Jankunas, Justin, Bertsche, Benjamin, Jachymski, Krzysztof, Hapka, Michal, Osterwalder, Andreas
Rok vydání: 2014
Předmět:
Zdroj: J. Chem. Phys. 140, 244302 (2014)
Druh dokumentu: Working Paper
DOI: 10.1063/1.4883517
Popis: Two isotopic chemical reactions, $\mathrm{Ne}^*$ + NH$_3$, and $\mathrm{Ne}^*$ + ND$_3$, have been studied at low collision energies by means of a merged beams technique. Partial cross sections have been recorded for the two reactive channels, namely $\mathrm{Ne}^*$ + NH$_3$ $\rightarrow$ Ne + NH$_3^+$ + $e^-$, and $\mathrm{Ne}^*$ + NH$_3$ $\rightarrow$ Ne + NH$_2^+$ + H + $e^-$, by detecting the NH$_3^+$ and NH$_2^+$ product ions, respectively. The cross sections for both reactions were found to increase with decreasing collision energy, $E_{coll}$, in the range 8 $\mu$eV$
Databáze: arXiv