Kinetics of the elementary act of electrochemical reactions at the semiconductor--electrolyte solution interface

Autor:	Kovalenko, Sergii, Soloviev, Veniamin
Rok vydání:	2013
Předmět:	Physics - Chemical Physics Condensed Matter - Materials Science
Zdroj:	Z. Naturforsch. A. 69a (2014) 654-658
Druh dokumentu:	Working Paper
DOI:	10.5560/ZNA.2014-0063
Popis:	In the framework of the quantum-mechanical theory of elementary act of non-adiabatic electrochemical reactions, it is carried out the calculation of the discharge current of ions at the semiconductor--electrolyte solution interface using the model of isotropic spherically symmetric band. It is shown that our results generalize the well-known formulae for the current density obtained by Dogonadze, Kuznetsov, and Chizmadzhev [R.R. Dogonadze, A.M. Kuznetsov, and Yu.A. Chizmadzhev, The kinetics of some heterogeneous reactions at semiconductor--electrolyte interface, Zhur. Fiz. Khim. 38 (1964) 1195--1202]. The average densities of states in the valence band and the conduction band of the semiconductor electrode in the heterogeneous charge transfer are found. Comment: Published version
Databáze:	arXiv
Externí odkaz:	http://arxiv.org/abs/1311.0639 Zobrazit plný text záznamu View this record from Arxiv