Comment on 'generalized Gibbs' approach' [J. Chem. Phys. 119, 6166 (2003); 124, 194503 (2006)]

Autor:	Alekseechkin, Nikolay V.
Rok vydání:	2012
Předmět:	Physics - Chemical Physics
Druh dokumentu:	Working Paper
Popis:	"Generalized Gibbs' approach" of Schmelzer et al [J. Chem. Phys. 119, 6166 (2003); 124, 194503 (2006)] results in wrong conditions of equilibrium of a critical embryo with the ambient phase. The presented analysis shows the shortcomings of this approach and proves the thermodynamic conditions of equilibrium. Also, a generalized adsorption equation is obtained in different forms. Comment: 8 pages
Databáze:	arXiv
Externí odkaz:	http://arxiv.org/abs/1211.1085 Zobrazit plný text záznamu View this record from Arxiv