The crystal and magnetic structure of the magnetocaloric compound FeMnP0.5Si0.5

Autor:	Höglin, Viktor, Hudl, Matthias, Sahlberg, Martin, Nordblad, Per, Beran, Premysl, Andersson, Yvonne
Rok vydání:	2011
Předmět:	Condensed Matter - Materials Science
Druh dokumentu:	Working Paper
DOI:	10.1016/j.jssc.2011.06.019
Popis:	The crystal and magnetic structure of the magnetocaloric compound FeMnP0.5Si0.5 have been studied by means of neutron and X-ray powder diffraction. Single phase samples of nominal composition FeMnP0.5Si0.5 have been prepared by the drop synthesis method. The compound crystallizes in the Fe2P-type structure (P-62m) with the magnetic moments aligned along the aaxis. It is found that the Fe atoms are mainly situated in the tetrahedral 3g site while the Mn atoms prefer the pyramidal 3f position. The material is ferromagnetic (TC = 382 K) and at 296 K the total magnetic moment is 4.4 \mu B/f.u. It is shown that the magnetic moment in the 3f site is larger (2.5 \mu B) than in the 3g site (1.9 \mu B). Comment: 8 pages, 4 figures
Databáze:	arXiv
Externí odkaz:	http://arxiv.org/abs/1105.1942 Zobrazit plný text záznamu View this record from Arxiv