Fragile-to-Strong Crossover in Supercooled Liquids Remains Elusive
Autor: | Elmatad, Yael S. |
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Rok vydání: | 2011 |
Předmět: | |
Druh dokumentu: | Working Paper |
DOI: | 10.1073/pnas.1103757108 |
Popis: | A critique of a recent paper [Mallamace et al PNAS 2010 107 (52) 22457-2246] purporting the existence of a fragile-to-strong crossover in super cooled liquids is presented. It is shown that Mallamace et al have mistaken the onset crossover with the fragile-strong crossover. Moreover, it is shown that supercooled liquid transport data follows the expected parabolic function, without a crossover to another functional form, and that Mallamace et al have obscured this fact by singling out anomalous data as examples. Comment: 1 figure |
Databáze: | arXiv |
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