Graphene on insulating crystalline substrates

Autor: Akcoeltekin, S., Kharrazi, M. El, Koehler, B., Lorke, A., Schleberger, M.
Rok vydání: 2009
Předmět:
Zdroj: Nanotechnology 20, 155601 (2009)
Druh dokumentu: Working Paper
DOI: 10.1088/0957-4484/20/15/155601
Popis: We show that it is possible to prepare and identify ultra--thin sheets of graphene on crystalline substrates such as SrTiO$_3$, TiO$_2$, Al$_2$O$_3$ and CaF$_2$ by standard techniques (mechanical exfoliation, optical and atomic force microscopy). On the substrates under consideration we find a similar distribution of single, bi- and few layer graphene and graphite flakes as with conventional SiO$_2$ substrates. The optical contrast $C$ of a single graphene layer on any of those substrates is determined by calculating the optical properties of a two-dimensional metallic sheet on the surface of a dielectric, which yields values between $C=$ ~- 1.5% (G/TiO$_2$) and $C=$ ~- 8.8% (G/CaF$_2$). This contrast is in reasonable agreement with experimental data and is sufficient to make identification by an optical microscope possible. The graphene layers cover the crystalline substrate in a carpet-like mode and the height of single layer graphene on any of the crystalline substrates as determined by atomic force microscopy is $d_{SLG}=0.34$ nm and thus much smaller than on SiO$_2$.
Comment: 7 pages, 4 figures
Databáze: arXiv