PİRİDİN-2,6-DİKARBOKSİLİK ASİTİN PROTON TRANSFER TUZU VE BUNUN Ni(II) VE Cu(II) KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU
| Autor: | BÜYÜKKIDAN, Nurgün, BÜYÜKKIDAN, Bülent, DEMİR, Nedime, KARAHAN, Ceyda |
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| Jazyk: | turečtina |
| Rok vydání: | 2018 |
| Předmět: | |
| Zdroj: | Issue: 041 1-12 Journal of Science and Technology of Dumlupınar University |
| ISSN: | 2651-2769 |
| Popis: | In this study the proton transfer salt (H2Meppz)(Hdipic)2 (1) was obtained by the reaction of N-methylpiperazine(Meppz) with pyridine-2,6-dicarboxylic acid (H2dipic). The metalcomplexes [Ni(H2O)6][Ni(dipic)2].(Meppz).5H2O(2) and (H2Meppz)[Cu(dipic)2].2H2O(3) were synthesized by the reactionof proton transfer salt (1) with Ni(CH3COO)2.4H2Oand Cu(CH3COO)2.2H2O.The structure of proton transfer salt (1) was characterized by 1H and 13CNMR, FT-IR and UV-Vis spectra and elemental analysis techniques. The structuresof the complexes have been suggested according to data obtained from FT-IR,UV-Vis, ICP-OES, magnetic susceptibility and elemental analysis methods. Bu çalışmada piridin-2,6-dikarboksilik asitin (H2dipic), N-metilpiperazin (Meppz) ilereaksiyonundan proton transfer tuzu (H2Meppz)(Hdipic)2 (1) elde edilmiştir. Elde edilenproton transfer tuzunun (1) Ni(CH3COO)2.4H2Ove Cu(CH3COO)2.H2O ile reaksiyonundan ise metal kompleksleri [Ni(H2O)6][Ni(dipic)2].(Meppz).5H2O(2) ve (H2Meppz)[Cu(dipic)2].2H2O(3) sentezlenmiştir. Protontransfer tuzunun (1) yapısı FT-IR, 1Hve 13C NMR, ve UV-Vis spekroskopileri ve elementel analiz teknikleriile aydınlatılmıştır. Komplekslerin yapıları ise FT-IR, UV-Vis, ICP-OES,manyetik duyarlılık ve elementel analiz yöntemlerinden elde edilen verileregöre önerilmiştir. |
| Databáze: | OpenAIRE |
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