Synthesis and Characterization of Conducting Copolymers of 4- aminobenzo-15-crown-5 with thiophene-3-carbaldehyde with 3,4- ethylenedioxythiophene

Autor: ŞAHİN IŞGIN, Elif, ŞAHMETLİOĞLU, Ertuğrul, TURAÇ, Ersen, DEMİR, İbrahim
Rok vydání: 2012
Předmět:
Zdroj: Volume: 14, Issue: 1 50-56
Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi
ISSN: 1301-7985
2536-5142
Popis: Bu kondenzasyon tepkimesi ile yeni bir 4’ (N-(Tiyofen-3-il metilen) benzenamin)-15-taç-5 eter (TAE) monomeri sentezlendi. TAE’nin 3,4-etilendioksitiyofen (EDOT) elektriksel olarak iletken kopolimeri elektrokimyasal yöntem ile sentezlendi. Kopolimerin karakterizasyonu; dönüşümlü voltametri (CV), Fourier transform infrared spektroskopi (FTIR), termal gravimetrik ısıl analizi (TGA), taramalı elektron mikroskopi (SEM) yöntemleri ile yapıldı
In this study a new 4’ (N-(Thiophen-3-yl methylene) benzenamine-15-crown-5 ether (TAE) monomer was synthesized by condensation reaction between 4-aminobenzo-15crown-5 with thiophene-3-carbaldehyde. Electrically conducting copolymer of TAE with 3,4-ethylenedioxythiophene (EDOT) was achieved by electrochemical methods. Characterization of the copolymer was performed by cyclic voltammetry (CV), Fourier transform infrared spectroscopy (FTIR),thermal gravimetric analysis (TGA), scanning electron microscopy (SEM) methods
Databáze: OpenAIRE