Synthesis and Characterization of Conducting Copolymers of 4- aminobenzo-15-crown-5 with thiophene-3-carbaldehyde with 3,4- ethylenedioxythiophene
Autor: | ŞAHİN IŞGIN, Elif, ŞAHMETLİOĞLU, Ertuğrul, TURAÇ, Ersen, DEMİR, İbrahim |
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Rok vydání: | 2012 |
Předmět: | |
Zdroj: | Volume: 14, Issue: 1 50-56 Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi |
ISSN: | 1301-7985 2536-5142 |
Popis: | Bu kondenzasyon tepkimesi ile yeni bir 4’ (N-(Tiyofen-3-il metilen) benzenamin)-15-taç-5 eter (TAE) monomeri sentezlendi. TAE’nin 3,4-etilendioksitiyofen (EDOT) elektriksel olarak iletken kopolimeri elektrokimyasal yöntem ile sentezlendi. Kopolimerin karakterizasyonu; dönüşümlü voltametri (CV), Fourier transform infrared spektroskopi (FTIR), termal gravimetrik ısıl analizi (TGA), taramalı elektron mikroskopi (SEM) yöntemleri ile yapıldı In this study a new 4’ (N-(Thiophen-3-yl methylene) benzenamine-15-crown-5 ether (TAE) monomer was synthesized by condensation reaction between 4-aminobenzo-15crown-5 with thiophene-3-carbaldehyde. Electrically conducting copolymer of TAE with 3,4-ethylenedioxythiophene (EDOT) was achieved by electrochemical methods. Characterization of the copolymer was performed by cyclic voltammetry (CV), Fourier transform infrared spectroscopy (FTIR),thermal gravimetric analysis (TGA), scanning electron microscopy (SEM) methods |
Databáze: | OpenAIRE |
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