Solidification of Ni-Re Peritectic Alloys

Autor: BOETTINGER, W.J., NEWBURY, D.E., RITCHIE, N.W.M., WILLIAMS, M.E., KATTNER, U.R., LASS, E.A., MOON, K.-W., KATZ, M.B., PEREPEZKO, J.H.
Rok vydání: 2020
Předmět:
Zdroj: Metall Mater Trans A Phys Metall Mater Sci
ISSN: 1543-1940
Popis: Differential thermal analysis (DTA) and microstructural and microprobe measurements of DTA and as-cast Ni-Re alloys with compositions between 0.20 and 0.44 mass fraction Re provide information to resolve differences in previously published Ni-Re phase diagrams. This investigation determines that the peritectic invariant between liquid, Re-rich hexagonal close packed and Ni-rich face center cubic phases, L + HCP → FCC, occurs at 1561.1 °C ± 3.4 °C (1σ) with compositions of liquid, FCC and HCP phases of 0.283 ± 0.036, 0.436 ± 0.026, and 0.828 ± 0.037 mass fraction Re, respectively. Analysis of the microsegregation in FCC alloys yields a partition coefficient for solidification, k = 1.54 ± 0.09 (mass frac./mass frac.). A small deviation from Scheil behavior due to dendrite tip kinetics is documented in as-cast samples. No evidence of an intermetallic phase is observed.
Databáze: OpenAIRE