Homoleptic lanthanide(II)-bis(guanidinate) complexes, [Ln(Giso)(2)] (Giso = [(ArN)(2)CN(C(6)H(11))(2)](-), Ar = C(6)H(3)Pr(i)(2)-2,6): planar 4-coordinate (Ln = Sm or Eu) vs distorted tetrahedral (Ln = Yb) geometries
Autor: | Dennis Heitmann, Cameron Jones, Peter Courtney Junk, Kai-Alexander Lippert, Andreas Stasch |
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Rok vydání: | 2006 |
Zdroj: | University of St Andrews CRIS |
ISSN: | 1477-9226 |
Popis: | The first homoleptic lanthanide(II)-guanidinate complexes have been prepared and shown to have differing coordination geometries (including unprecedented examples of planar 4-coordination) that depend on the size of the lanthanide metal. |
Databáze: | OpenAIRE |
Externí odkaz: |
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