Chemical and Structural Stability of Zirconium-based Metal–Organic Frameworks with Large Three-Dimensional Pores by Linker Engineering**

Autor: Kalidindi, Suresh B, Nayak, Sanjit, Briggs, Michael E, Jansat, Susanna, Katsoulidis, Alexandros P, Miller, Gary J, Warren, John E, Antypov, Dmytro, Cora, Furio, Slater, Ben, Prestly, Mark R, Marti-Gastaldo, Carlos, Rosseinsky, Matthew J
Jazyk: angličtina
Rok vydání: 2014
Předmět:
Zdroj: Angewandte Chemie (International Ed. in English)
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN: 1521-3773
1433-7851
Popis: The synthesis of metal-organic frameworks with large three-dimensional channels that are permanently porous and chemically stable offers new opportunities in areas such as catalysis and separation. Two linkers (L1=4,4',4'',4'''-([1,1'-biphenyl]-3,3',5,5'-tetrayltetrakis(ethyne-2,1-diyl)) tetrabenzoic acid, L2=4,4',4'',4'''-(pyrene-1,3,6,8-tetrayltetrakis(ethyne-2,1-diyl))tetrabenzoic acid) were used that have equivalent connectivity and dimensions but quite distinct torsional flexibility. With these, a solid solution material, [Zr6 O4 (OH)4 (L1)2.6 (L2)0.4 ]⋅(solvent)x , was formed that has three-dimensional crystalline permanent porosity with a surface area of over 4000 m(2) g(-1) that persists after immersion in water. These properties are not accessible for the isostructural phases made from the separate single linkers.
Databáze: OpenAIRE
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